2023
60) Perera, T. A.; Taylor, W. V.; Gildner, M. B.; Reinheimer, E. W.; Ito, S.; Nelson, A.; Yost, S. R.; Hudnall. T. W.* Photochemical Reactions of a Diamidocarbene: Cyclopropanation of Bromonaphthalene, Addition to Pyridine, and Activation of sp3 C–H Bonds Chem. Sci. 2023, Accepted Artivle. Link to Article
59) Ledet, A. D.; Reinheimer, E. W.; Hudnall. T. W.* A Diamidocarbene-Supported Aminoborylene: Characterization and Discussion of the Elusive Crystal Structure J. Chem. Cryst. 2023, 53, 112-116.
58) Rodrigues, R. R.; Reinheimer, E. W.; Dorsey, C. L.; Hudnall. T. W.* Synthesis of a tetratopic bisphosphine ligand derived from pyrimidine and its incorporation into gold and silver coordination polymers Inorg. Chim. Acta 2023, 546, 121209. Link to Article
2021
57) Hudnall. T. W.*; Reinheimer, E. W.; Dorsey, C. L. Synthesis, crystal structure determination, and spectroscopic analyses of 1-chloro-2-(2,6-diisopropylphenyl)-4,4-dimethyl-2-azaspiro[5.5]undecane-3,5-dione: an unyielding precursor to a cyclic (alkyl)(amido)carbene Acta Cryst. C. 2021, 77(7), 411-419. Link to Article
56) Koh, D.; Hudnall. T. W.; Bielawski, C. W.; Banerjee, S. K.*; Brockman, J.; Kuhn, M.; King, S. W.* X-ray photoemission investigation of the beryllium oxide band alignment with magnesium oxide and estimates for other insulating and conducting oxides ECS Transactions 2021, 102(3), 127-138. Link to Article
55) Rastogi, S. K.*; Zhao, Z.; Gildner, M. B.; Shoulders, B. A.; Velasquez, T. L.; Blumenthal, M. O.; Wang, L.; Li, X.; Hudnall, T. W.; Betancourt, T.l Du, L.; Brittain, W. J. Synthesis, optical properties andin vitrocell viability of novelspiropyrans and their photostationary states Tetrahedron 2021, 80, 131854.
2020
54) Koh, D.; Hudnall. T. W.; Bielawski, C. W.; Banerjee, S. K.*; Brockman, J.; Kuhn, M.; King, S. W.* X-ray photoelectron spectroscopy investigation of the valence band offset at beryllium oxide-diamond interfaces Diamond and Related Materials 2020, 110,107647.
53) Wang, L.*; Liu, L.; Chen, C.; Mohsin, A.; Yum, J. H.; Hudnall, T. W.; Bielawski, C. W.; Rajh, T.; Bai, X.; Gao, S.-P.*; Gu, G.* Synthesis of Honeycomb-Structured Beryllium Oxide via Graphene Liquid Cells Angew. Chem. Int. Ed. 2020, 59, 15734-15740.
2019
52) Koh, D.; Banerjee, S. K.; Hudnall, T. W.; Bielawski, C. W.; Locke, C.; Saddow, S. E.; Brockman, J.; Kuhn, M.; King, S. W. * Valence and Conduction Band Offsets at Beryllium Oxide Interfaces with Silicon Carbide and III-V Nitrides J. Vac. Sci. Technol. B 2019, 37, 041206. Link to Article
51) van Rixel, V. H. S.; Ramu, V.; Auyeung, A. B.; Beztsinna, N.; Léger, D. Y.; Hilt, S. T.; Le Dévédec, S. E.; Yildiz, T.; Betancourt, T.; Gildner, M.B.; Hudnall, T. W; Sol, V.; Liagre, B.; Kornienko, A.*; Bonnet, S.* Photo-uncaging of a ruthenium-caged microtubule-targeted rigidin analogue in hypoxic cancer cells and in a xenograft mouse model J. Am. Chem. Soc. 2019, 141, 19444 – 18454. Link to Article
50) Gildner, M.B.; Hudnall, T. W.* Cyclic (aryl)(amido)carbenes: pushing the p-acidity of amidocarbenes through benzannulation Chem. Commun. 2019, 55, 12300-12303. Link to Article
49) Dasari, R.; Blauz, A.; Medellin, D. C.; Kassim, R. M.; Viera, C.; Santarosa, M.; van der Westhuyzen, A. E.; van Otterlo, W. A. L.; Olivas, T.; Yilidiz, T.; Betancourt, T.; Shuster, C. B.; Rogelj, S.; Rychlik, B.*; Hudnall, T. W.*; Frovola, L. V.*; Kornienko, A.* Microtubule-Targeting 7-Deazahypoxanthines Derived from Marine Alkaloid Rigidins: Exploration of the N3 and N9 Positions and Interaction with Multidrug-Resistance Proteins ChemMedChem 2019, 14, 322-333.
2018
48) Melancon, K. M.; Gildner M. B.; Hudnall, T. W.* Synthesis, Spectroscopic Characterization, and Redox Reactivity of a Cyclic (Alkyl) Amino Carbene-Derived Arsamethine Cyanine Dye. Chem – Eur. J. 2018, 24, 9264-9268.
47) Govindaraju, K.; Masi, M.; Colin, M.; Mathieu, V.; Evidente, A.; Hudnall, T. W.*; Kornienko, A.* Novel Topologically Complex Scaffold Derived from Alkaloid Haemanthamine. Molecules, 2018, 23, 255-263.
2017
46) Perera, T. A.; Reinheimer, E. W.; Hudnall, T. W.* Photochemically Switching Diamidocarbene Spin States Leads to Reversible Buchner Ring Expansions. J. Am. Chem. Soc., 2017, 139, 14807-14814.
45) Ugarte, R. A. and Hudnall, T. W.* Antimony(V) catalyzed acetalisation of aldehydes: an efficient, solvent-free, and recyclable process. Green Chemistry, 2017, 19, 1990-1998.
44) Neier, E.; Ugarte, R. A.; Rady, N.; Venkatensan, S.; Hudnall, T. W.*; Zakhidov, A.* Solution-Processed Organic Light-Emitting Diodes with Emission from a Doublet Exciton Using (2,4,6-trichlorophenyl)methyl as an Emitter Organic Electronics, 2017,44, 126-131.
2016
43) Hamon, C. L.; Dorsey, C. L.; Özel, T.; Barnes, E. M.; Hudnall, T. W. and Betancourt, T.* Near-infrared fluorescent aza-BODIPY dye-loaded biodegradable polymeric nanoparticles for optical cancer imaging J. Nanopart. Res.. 2016, 18, 207-218.
42) Ugarte, R. A.; Devarajan, D.; Mushinski, R. M. and Hudnall, T. W.* Antimony(V) Cations for the Selective Catalytic Transformation of Aldehydes Into Symmetric Ethers, a,b-Unsaturated Aldehydes, and 1,3,5-Trioxanes Dalton Trans. 2016, 45, 11150-11161.
41) Ledet, A. D. and Hudnall, T. W.* Reduction of a Diamidocarbene-Supported Borenium Cation: Isolation of a Neutral Boryl-Substituted Radical and a Carbene-Stabilized Aminoborylene Dalton Trans. 2016, 45, 9820-9826. (invited manuscript for the 2016 themed issue – New Talent: Americas).
40) Hudnall, T. W.*; Dorsey, C. L.; Jones, J. S.; Gabbaï, F. P.* Stepwise Reduction of an α-Phosphonio-Carbocation to a Crystalline Phosphorus Radical Cation and an Acridinyl-Phosphorus Ylide Chem – Eur. J. 2016, 22, 2882-2886. Featured on Frontispiece.
39) Deardorff, C. L.; Sikma, R. E.; Rhodes, C. P.; Hudnall, T. W.* Carbene-derived α-acyl formamidinium cations: organic molecules with readily tunable multiple redox processes Chem. Commun. 2016, 52, 9024-9027. (invited manuscript for the 2016 Emerging Investigators special issue).
2015
38) Montalvo, S. J.; Hudnall, T. W.; Feakes, D. A.* Exploring the redox reactivity of the [B20H18]2- ion with carbon-based nucleophiles and electrophiles J. Organomet. Chem. 2015, 798, 141-145.
2014
37) Dorsey, C. L.; Mushinski, R. M.; Hudnall, T. W.* Metal-Free Stabilization of Monomeric Antimony(I): A Carbene-Supported Stibinidene. Chem. – Eur. J. 2014, 20, 8914-8917.
36) Torres, A. J.; Dorsey, C. L.; Hudnall, T. W.* Preparation and Use of Carbonyl-Decorated Carbenes in the Activation of White Phosphorus. J. Vis. Exp. 2014, 92 e52149, doi:10.3791/52149. Link to Article
35) Koh, D.; Kwon, H. M.; Kim, T.-W.*; Kim, D.-H.; Hudnall, T. W.; Bielawski, C. W.; Maszara, W.; Veksler, D.; Gilmer, D.; Kirsch, P. D.; Banerjee, S. K. Lg = 100 nm In0.7Ga0.3As quantum well metal-oxide semiconductor field-effect transistors with atomic layer deposited beryllium oxide as interfacial layer. App. Phys. Lett. 2014, 104, 163502-1 – 163502-4.
34) Koh, D. Yum, J. H.; Banerjee, S. K.; Hudnall, T. W.; Bielawski, C. W.l LAngford, W. A.; French, B. L.; French, M.; Henry, P.; Li, H.; Kuhn, M.; King, S. W.* Investigation of Atomic Layer Deposited Beryllium Oxide Material Properties for High-K Dielectric Applications. J. Vac. Sci. Technol. B 2014, 32, 03D117.
33) Min, K. S.; Kang, S. H.; Kim, J. K.; Yum, J. H.; Jhon, Y. I.; Hudnall, T. W.; Bielawski, C. W.; Banerjee, S. K.; Bersuker, G.; Jhon, M. S.; Yeom, G. Y.* Atomic layer etching of BeO using BCl3/Ar for the interface passivation layer of III-V MOS devices. Microelectron. Eng. 2014, 114, 121-125.
32) Johnson, D.W.; Yum, J.H.; Hudnall, T.W.; Mushinski, R.M.; Bielawski, C. W.; Roberts, J.C.; Wang, W.E.; Banerjee, S.K.; Harris, R. Characterization of ALD Beryllium Oxide as a Potential High-k Gate Dielectric for Low-Leakage AlGaN/GaN MOSHEMTs. J. Electron. Mater. 2014, 43, 151-154.
31) Rodrigues, R. R.; Dorsey, C. L.; Arceneaux, C. A.; Hudnall T. W.* Phosphaalkene vs. Phosphinidene: The Nature of the P–C Bond in Carbonyl-Decorated Carbene→PPh Adducts. Chem. Commun. 2014, 50, 162-164. Featured on Back Cover
2013
30) Shin, H. S.; Yum, J. H.; Johnson, D. W.; Harris, H. R.; Hudnall, T. W.; Oh, J.; Kirsch, P.; Wang, W.-E.; Bielawski, C. W.; Banerjee, S. K.; Lee, J. C.; Lee, H. D.* Low interface defect density of atomic layer deposited BeO with self-cleaning reaction for InGaAs metal oxide semiconductor field effect transistors. App. Phys. Lett. 2013, 103, 223504/1-223504/3.
29) Douglas, N.; Neef, C. J.; Rogers, R. A.; Stanley, J. A.; Armitage, J.; Martin, B.; Hudnall, T. W.; Brittain, W. J.* Reactivity of tetrahydrochromeno[2,3-b] indoles: chromic indicators of cyanide. J. Phys. Org. Chem. 2013, 26, 688–695.
28) Dorsey, C. L.; Squires, B. M.; Hudnall, T. W.* Isolation of a Neutral P8 Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus. Angew. Chem. Int. Ed. 2013, 52, 4462–4465. Featured on Inside Front Cover
2012
27) Yum. J. H.*; Shin, H. S.; Hill, R.; Oh, J.; Lee, H. D.; Mushinski, R. M.; Hudnall, T. W.; Bielawski, C. W.; Banerjee, S. K.; Loh, W. Y.; Wang, W. E.; Kirsch, P. A study of capping layers for sulfur monolayer doping on III-V junctions. App. Phys. Lett. 2012, 101, 253514-1–253514-3.
26) Yum, J. H.*; Oh, J.; Hudnall, T. W.; Bielawski, C. W.; Bersuker, G.; Banerjee, S. K. Comparative study of SiO2, Al2O3, and BeO ultrathin interfacial barrier layers in Si metal-oxide-semiconductor devices. Active and Passive Electronic Components 2012, 359580, 7 pages.
25) Mushinski, R. M.; Squires, B. M.; Sincerbox, K. A.; Hudnall, T. W.* Amino-Acrylamido Carbenes: Modulating Carbene Reactivity via Decoration with an α,β-unsaturated Carbonyl Moiety. Organometallics 2012, 31, 4862-7870.
24) Lei, M.; Yum, J. H.*; Price, J.; Hudnall, T. W.; Bielawski, C. W.; Banerjee, S. K.; Lysaght, P. S.; Bersuker, G.; Downer, M. C. Spectroscopic evaluation of band alignment of atomic layer deposited BeO on Si(100). App. Phys. Lett. 2012, 100, 122906-1–122906-4.
23) Yum, J. H.*; Akyol, T.; Lei, M.; Ferrer, D. A.; Hudnall, T. W.; Bielawski, C. W.; Bersuker, G.; Lee, J. C.; Banerjee, S. K. Electrical and Physical Characteristics for Crystalline Atomic Layer Deposited Beryllium Oxide Thin Film on Si and GaAs Substrates. Thin Solid Films 2012, 520, 3091–3095.
2011
22) Yum, J. H.*; Bersuker, G.; Akyol, T.; Ferrer, D. A.; Lei, M.; Park, K. W.; Hudnall, T. W.; Downer, M. C.; Bielawski, C. W.; Yu, E. T.; Price, J.; Lee, J. C.; Banerjee, S. K. Epitaxial ALD BeO: Efficient Oxygen Diffusion Barrier for EOT Scaling and Reliability Improvement. IEEE Trans. Electron Devices 2011, 58, 4384–4392.
21) Yum, J. H.*; Akyol, T.; Lei, M.; Ferrer, D. A.; Hudnall, T. W.; Downer, M.; Bielawski, C. W.; Bersuker, G.; Lee, J. C.; Banerjee, S. K. A study of highly crystalline novel beryllium oxide film using atomic layer deposition. J. Cryst. Growth 2011, 334, 126-133. Link to Article
20) Yum, J. H.*; Akyol, T.; Ferrer, D. A.; Banerjee, S. K.; Lei, M.; Downer, M.; Hudnall, T. W.; Bielawski, C. W.; Bersuker, G. Comparison of Self Cleaning Effect and Electrical Characteristics between Atomic Layer Deposited BeO and Al2O3 as an Interface Passivation Layer on GaAs MOS Devices. J. Vac. Sci. Technol. A. 2011, 29, 061501-1–061501-6. Link to Article
19) Yum, J. H.*; Akyol, T.; Lei, M.; Ferrer, D. A.; Hudnall, T. W.; Downer, M.; Bielawski, C. W.; Bersuker, G.; Lee, J. C.; Banerjee, S. K. Inversion type InP metal oxide semiconductor field effect transistor using novel atomic layer deposited BeO gate dielectric. Appl. Phys. Lett. 2011, 99, 033502-1–033502-3. Link to Article
18) Li, Z.*; Lin, T.-P.; Lui, S.; Huang, C.-W.; Hudnall, T. W.; Gabbaï, F. P.*; Conti, P. S. Rapid aqueous [18F]-labeling of a bodipy dye for positron emission tomography/fluorescence dual modality imaging. Chem. Commun. 2011, 47, 9324–9326. Link to Article
17) Yum, J. H.*; Akyol, T.; Lei, M.; Hudnall, T.; Bersuker, G.; Downer, M.; Bielawski, C. W.; Lee, J. C.; Banerjee, S. K. Atomic layer deposited beryllium oxide: Effective passivation layer for III-V metal/oxide/semiconductor devices. J. Appl. Phys. 2011, 109, 064101-1–064101-4. Link to Article
2010
16) Hudnall, T. W.; Tennyson, A. G.; Bielawski, C. W.* A Seven-Membered N,N’-Diamidocarbene. Organometallics 2010, 29, 4569–4578. Link to Article
15) Park, J. S.; Karnas, E.; Ohkubo, K.; Chen, P.; Kadish, K. M.; Fukuzumi, S.; Bielawski, C. W.*; Hudnall, T. W.; Lynch, V. M.; Sessler, J. L.* Ion-Mediated Electron Transfer in a Supramolecular Donor-Acceptor Ensemble. Science 2010, 329, 1324–1326. Link to Article
14) Hudnall, T. W.; Lin, T.-P.; Gabbaï, F. P.* Substitution of Hydroxide by Fluoride at the Boron Center of a BODIPY Dye. J. Fluo. Chem. 2010, 131, 1182–1186. Link to Article
13) Hudnall, T. W.; Moerdyk, J. P.; Bielawski, C. W.* Ammonia N–H Activation by a N,N‘–Diamidocarbene. Chem. Commun. 2010, 46, 4288-4290. Link to Article
12) Hudnall, T. W.; Moorhead, E. J.; Gusev, D. G.; Bielawski, C. W.* N,N’-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene. J. Org. Chem. 2010, 75(8), 2763-2766. Link to Article
11) Tennyson, A. G.; Ono, R. J.; Hudnall, T. W.; Khramov, D. M.; Er, J. A. V.; Kamplain, J. W.; Lynch, V. M.; Sessler, J. L.*; Bielawski, C. W.* Quinobis(imidazolylidene): Synthesis and study of an electron-configurable bis(N-heterocyclic carbene) and its bimetallic complexes. Chem. – Eur. J. 2010, 16 (1), 304-315. Link to Article
2009
10) Hudnall, T. W.; Bielawski, C. W.* An N,N’-Diamidocarbene: Studies in C–H insertion, Reversible Carbonylation and Transition-Metal Coordination Chemistry. J. Am. Chem. Soc. 2009, 131(44), 16039-16041. Link to Article
9) Kim, Y.; Hudnall, T. W.; Bouhadir, G. B.; Bourissou, D.; Gabbaï, F. P.* Azide ion recognition in water/CHCl3 using a chelating phosphonium borane as a receptor. Chem. Commun. 2009, 3729-3731. Link to Article
8) Hudnall, T. W.; Chiu, C.-W.; Gabbaï, F. P.* Fluoride ion recognition by chelating and cationic boranes. Acc. Chem. Res. 2009, 42(2), 388-397. Link to Article
2008
7) Hudnall, T. W.; Kim, Y.; Bebbington, M. W. P.; Bourissou, D.; Gabbaï, F. P.* Fluoride ion chelation by a bidentate phosphonium/borane Lewis acid. J. Am. Chem. Soc. 2008; 130(33), 10890-10891. Link to Article
6) Hudnall, T. W.; Gabbaï, F. P.* A BODIPY boronium cation for the sensing of fluoride ions. Chem. Commun. 2008, 4596-4597. Link to Article
5) Dorsey, C. L.; Jewula, P.; Hudnall, T. W.; Hoefelmeyer, J. D.; Taylor, T. J.; Honesty, N.; Chiu, C.-W.; Schulte, M.; Gabbaï, F. P.* Fluoride Ion Complexation by a B2/Hg heteronuclear Tridentate Lewis Acid – A Structural and Electrochemical Invesitgation. Dalton Trans. 2008, 33, 4442-4450. Link to Article
2007
4) Hudnall, T. W.; Gabbaï, F. P.* Ammonium boranes for the selective complexation of cyanide or fluoride ions in water. J. Am. Chem. Soc. 2007, 129(39), 11978-11986. Link to Article
2006
3) Hudnall, T. W.; Bondi, J. F.; Gabbaï, F. P.* ortho-Borylated trifluoroacetanilides – Synthesis and fluoride ion binding properties. Main Group Chemistry 2006, 5(4), 319-327. Link to Article
2) Hudnall, T. W.; Melaïmi, M.; Gabbaï, F. P.* A hybrid Lewis acid/hydrogen bond donor receptor for fluoride. Org. Lett. 2006, 8(13), 2747-2749. Link to Article
2004
1) Hoppens, N. C.; Hudnall, T. W.; Foster, A.; Booth, C. J.* Aliphatic-Aromatic Copolyesters Derived from 2,2,4,4-Tetramethyl-1,3- cyclobutanediol. J. Polym. Sci., Part A: Polym. Chem. 2004, 42(14), 3473-3478. Link to Article